Colorado Mountain College
Roaring Fork Campus
CHE 211 Organic Chemistry I
Chapter 9
Reading Assignment:
Solomons - Pages 366 - 402
Objectives:
Be knowledgeable about and capable of working problems in the following areas:
Homolytic Bond Dissociation and the Structure and Stability of Free Radicals
Free Radical Halogenation of Alkanes
- Mechanism
- Energetics and kinetics
- Reactivity vs. selectivity
- Stereochemical consequences
Free Radical Additions of HBr to Alkenes and the Peroxide Effect
- Mechanism
- Stereochemistry (Markovinkov vs. anit-Markonvnikov addition)
Free Radical Polymerization of alkenes
Other Selected Free Radical Reactions
Problem Assignment:
The following problems should be worked to assist you in meeting the Chapter Objectives.
Page Problem
369 9.1
373 9.2, 9.3
379 9.7, 9.8
383 9.9, 9.10
402 9.25
Tutorial Links
Detailed Chapter 9 Outline (at Ralph Logan's Page)
Tutorial in Organic Chemistry
Detailed Chapter Outline (at Dr. Kleinman's Page)
Organic Chemistry On-Line
Basic Organic Nomenclature (by Dr. Woodcock)
Peter Jeschofnig, Ph.D., Professor of Chemistry, Colorado Mountain College
Send Comments to Peter Jeschofnig:
All textual content copyrighted (c) 1997
Peter Jeschofnig, Colorado Mountain College
All Rights reserved
Revised: 9/23/97
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